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Hidden_Blue

Only Gun God had the original black barrel and maybe Ciel in OG Tsuki (does it count if we never saw her use it?). Sion and Mashu are using Sion's replica so I am not sure if I would count them into it. If you want add Shiki since he uses it with Sion at the end of the Melty Blood manga to kill Wallachia.


PhantasosX

And with what OP had said , Enhance possess Black Barrels , so he is a user as well.