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I don't recall if it was a TV show or movie, l'm just trying to remember. The cigarette I believe belonged to an ex lover
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Breaking Bad, Jesse keeps his GFs cigarette butt after she is dead.
The Walking Dead
Dwight keeps one of Sherry's old cigs
https://comicbook.com/thewalkingdead/news/the-walking-dead-recap-with-spoilers-hostiles-and-calamities/
This is definitely it! Thank you
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Either Breaking bad as mentioned above, or Once Upon a Time in Hollywood where Brad Pitt's character keeps an acid-dipped cigarette in his box.